Spectrophotometric determination of cerium with leuco xylene cyanol FF.
نویسندگان
چکیده
منابع مشابه
Simultaneous determination of trace iron and aluminum by catalytic spectrophotometry based on a novel oxidation reaction of xylene cyanol FF.
A new, simple, sensitive and selective method for the simultaneous determination of trace iron and aluminum by catalytic spectrophotometry was presented, based on the catalytic effects of iron and aluminum on the discoloring reaction of xylene cyanol FF proceeded by hydrogen peroxide and potassium periodate in weak nitric acid medium. No catalytic effect was obtained in the presence of hydrogen...
متن کاملDevelopment and Validation of Spectrophotomtric Method for the Determination of Risperidone
A simple and sensitive method for the spectrophotometric determination of risperidone (RIS) is proposed. The method is based on the oxidation of the drug using chloramine-T (CAT) and the excess oxidant is determined by either xylene cyanol FF (XCFF) or malachite green (MG), the absorbances of which are measured at 612 or 619 nm for RIS-XCFF and RIS-MG respectively. Under the proposed optimum co...
متن کاملExtraction and Spectrophotometric Determination of Cerium(IV) with N-p-Chlorophenylcinnamohydroxamic Acid
N-p-Chlorophenylcinnamohydroxamic acid reacts with cerium(IV) to form an orange coloured complex, quantitatively extractable into chloroform from alkaline medium. On the basis of this sensitive colour reaction, a new method for the extraction and spectrophotometric determination of cerium(IV) has been developed. The effects of foreign ions and sever al experimental variables on the extraction a...
متن کاملA NOVEL AND HIGHLY SENSITIVE CATALYTIC METHOD FOR THE DETERMINATION OF ULTRA TRACE AMOUNTS OF CERIUM WITH SPECTROPHOTOMETRIC DETECTION
Cerium (IV) has a catalytic effect on the very slow redox reaction between gallocyanine and bromate in acidic media. The reaction was monitored spectrophotometrically at 525 nm by a fixed time method of 4.0 rnin from initiation of the reaction. The decrease in absorbance at 525 nm is proportional to the Ce (IV) concentration in the range of 0.005-1.000 and 1.00-10.00 pg. ml-l. The limit of ...
متن کاملSpectrophotometric determination of cerium(IV) using a phenothiazine derivative.
A simple, rapid and sensitive spectrophotometric method has been proposed for the determination of cerium(IV) using a phenothiazine derivative, propionyl promazine phosphate (PPP). This method is based on the formation of a red-colored radical cation upon a reaction of PPP with cerium(IV) in a phosphoric acid medium having maximum absorbance at 513 nm. Beer's law is valid over the concentration...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Analytical sciences : the international journal of the Japan Society for Analytical Chemistry
دوره 18 11 شماره
صفحات -
تاریخ انتشار 2002